天津地区土壤中若干金属元素间的相关性
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CORRELATION BETWEEN ELEMENTS IN SOILS OF TIANJIN AREA
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    摘要:

    土壤中的元素主要来源于成土母质[1],但在风化成土过程中,元素的迁移与富集能力各不相同。为了寻求土壤中元素间的内在联系,判断元素的含量和分布状况,元素间的相关分析法是良好的方法之一。例如,Ure等[6]测定了苏格兰不同母质的土壤中多种微量元素含量,并讨论了各元素间的相互关系。Pilotte等[5]用相关性分析法对河口地区沉积物中元素含量进行判断,浅见辉男等[4]用元素相关性描述了沉积物中元素分布,梁伟[5]用元素相关性对土壤背景值进行判断等。本文根据天津地区土壤表土中16个元素之间的相关系数,探讨元素的地球化学性质对元素间的相关性的影响。

    Abstract:

    The correlation between elements in soils of Tianjin area was studied based on the analytical data of soil samples collected from this area including fluvo-aquic soil,salinized fluvo-aquic soil,boggy fluvo-aquic soil derived from alluvial deposits,lacustrine deposits and diluvial deposits,and cinnamon soils derived from granite,limestone,sandstone ete.The contents of Co,Ni,Li,Cd,Cu Cr and Pb were determined by AAS,those of Fe,Zn,Sr,Zr,Ti and Ca by XRF;that of As by Ag-DDTC speetrophotometry and that of Hg by cold vapour atomic absorption method.Correlation coefficients were calculated by the aid of statistical method with natural logarithm of analytical.data.Critical value of correlation coefficient was 0.254,which was calculated by the correlation detection method (α=0.01,n=103).According to the data obtained,the correlation coefficients are divided into four levels i,e,significantly correlated(|R|>0.75),better correlated (0.75>|R|>0.50),correlated (0.50>|R|>0.25),and incorrelated(|R|>0.25).The degree of correlation of elements is related to their geochemical characteristics.It is found that there is a positive correlation between the elements,if their geochemical characteristics are similar;while there is a negative correlation between them,if they are different in geochemical characteristics with different directions of their translocation and accumulation.In addition,in the soil forming process the organic matter,chemical and physical conditions,etc.can offeet the translocation,accumulation and degree of correlation of elements in soil.

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戴昭华,黄衍初.天津地区土壤中若干金属元素间的相关性[J].土壤学报,1984,21(3):314-319. Dai Zhaohua, Huang Yanchu. CORRELATION BETWEEN ELEMENTS IN SOILS OF TIANJIN AREA[J]. Acta Pedologica Sinica,1984,21(3):314-319.

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  • 在线发布日期: 2013-02-25
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