黄土性土壤在连续液流条件下吸附、解吸磷酸根的动力学研究
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KINETICS OF PHOSPHATE ADSORPTION-DESORPTION OF LESSIAL SOILS UNDER CONTINUOUS LIQUID CURRENT
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    摘要:

    采用连续液流法研究了黄土性土壤吸附、解吸磷酸根的动力学性质。结果表明:(1)供试土壤对磷酸根的吸附、解吸按速率可分为快、中、慢三种反应类型;(2)描述吸附、解吸反应的最优模型均为Elovich方程,最差模型分别为一级反应方程及双常数方程,拟合差的模型对反应速率变化“敏感”,可用于反应类型划分和机理研究;(3)粘粒含量及代换量对吸附速率有显着影响,游离铁对吸附速率、CaCO3对较低温度下的吸附及较高温度下的解吸速率也有明显影响,速效磷含量是控制解吸速率的重要因子;(4)升高温度吸附加速,但对解吸速率无明显影响;(5)不同土类及同一剖面不同层次的吸附、解吸速率,反应时间及吸附、解吸量不同。

    Abstract:

    Kinetics characteristics of phosphate adsorption-desorption by Loessial soils were studied under the conditions of continuous liquid current. Phosphate was adsorbed and desorbed at different rates. According to the rate, the reaction of adsorbing-desorbing could be divided into three types: fast, middle and slow reactions. Elovich equation was the best model to decribe the adsorption and desorption of phosphate, while the first-order and parabolic diffusion equations were the worst; but the worst models were "sensitive" to the changes of reaction rate and could be used to classify reaction type and to study the reaction meachanism. The rates of adsorption and desorption were closely related to the soil clay and CEC. The influences of free Fe2O3 on adsorbing rate and CaCO3 on adsorbing rate under lower temperature and desorbing rate under higher temperature were siginficant. The rapiddly available phosphorus was an important factor to control the desorption rate. The rate of phosphate adsorption was significantly influenced by temperature, but the effect of temperature on the desorption rate was not significant. The adsorption and desorption rates, capacit, of phosphate and reaction time varied with soil types and horizons.

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薛泉宏,尉庆丰,薛喜乐.黄土性土壤在连续液流条件下吸附、解吸磷酸根的动力学研究[J].土壤学报,1995,32(2):142-150. Xue Quanhong, Wei Qingfeng, Xue Xile. KINETICS OF PHOSPHATE ADSORPTION-DESORPTION OF LESSIAL SOILS UNDER CONTINUOUS LIQUID CURRENT[J]. Acta Pedologica Sinica,1995,32(2):142-150.

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  • 在线发布日期: 2013-02-25
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