On the basis of temperature influences on diffusion transmission factor(f) through influencing water viscosity (η), it was advanced that viscosity correction coefficient (κ) could be described by the equation κ=η25/ηo where η25 and ηx, stand for the water viscosity at 25℃ and x℃,respectively, and the modified Nye model to estimate the diffusion coefficient of phosphate in soil under varying temperature was in the form of D=D0κfθ/b. By using the adsorption isotherm slope (b) under a lower ratio of solution to soil and lower concentration of phosphate solution, the diffusion coefficient predicted by the model was in agreement with the diffusion coefficient measured, especially at indoor temperature. The ratio of the predicted phosphate diffusion coefficient to the measured phosphate diffusion coefficient in soil under low water tension condition(<105 Pa) was lower than 2 in most cases.
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徐明岗,张一平,孙本华.土壤磷扩散规律及其能量特征的研究 Ⅳ.土壤磷扩散的预测[J].土壤学报,1998,35(3):345-351. DOI:10.11766/trxb199504050308 Xu Ming-gang, Zhang Yi-ping, Sun Ben-hua. DIFFUSION OF PHOSPHATE IN SOILS Ⅳ. PREDICTION[J]. Acta Pedologica Sinica,1998,35(3):345-351.