低分子量有机酸对土壤磷释放动力学的影响
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*国家自然科学基金(批准号:39790100)


KINETICS OF PHOSPHORUS RELEASE FROM SOILS,AS AFFECTED BY ORGANIC ACIDS WITH LOW-MOLECULAR-WEIGHT
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    摘要:

    模拟植物在缺磷条件下,根系所分泌的有机酸种类和数量,用流动法研究了柠檬酸、苹果酸、草酸和酒石酸对土壤磷释放(解吸)的影响.结果表明:有机酸能明显促进土壤中磷的释放,不同有机酸对石灰性土壤磷活化能力大小的次序为草酸≥柠檬酸>苹果酸>酒石酸;而对酸性土壤磷的释放量与Fe+Al释放量之间呈极显著正相关,有机酸活化土壤磷能力大小的次序为柠檬酸>草酸>酒石酸>苹果酸.抛物线扩散方程能较好的拟合有机酸对土壤磷释放的动力学过程(r>094).在两种土壤上,柠檬酸和草酸均可明显地提高磷的相对扩散系数,而酒石酸只对酸性土壤磷的相对扩散系数有明显的提高作用.

    Abstract:

    A flow technique was applied to investigate the effect of organic acids with low-molecular-weight on phosphorus release from 3 soils:2 calcareous soils and 1 acidic soil (red earth).It was indicated that the release of soil phosphorus was significantly stimulated by organic acids for all of 3 soils tested.For calcareous soils, the ability of mobilizing soil phosphorus of organic acids followed the order:oxalic ≥ citric> malic>tartaric acid.As for red earth,the release of soil phosphorus was highly correlated with soil aluminum and iron extracted,and the mobilizing ability of organic acids for phosphorus followed the order:citric>oxalic>malic>tartaric acid.Regression analysis revealed,that parabolic diffusion equation was applicable to describe the release kinetics of soil phosphorus,as affected by organic acids (r>0.94). Both citric and oxalic acids increased the P diffusion coefficients significantly in all of 3 soils.However,remarkable increase of P diffusion coefficients by tartaric acid only occurred in acidic soil.

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陆文龙,王敬国,曹一平,张福锁.低分子量有机酸对土壤磷释放动力学的影响[J].土壤学报,1998,35(4):493-500. DOI:10.11766/trxb199707120408 Lu Wen-long, Wang Jing-guo, Cao Yi-ping, Zhang Fu-suo. KINETICS OF PHOSPHORUS RELEASE FROM SOILS, AS AFFECTED BY ORGANIC ACIDS WITH LOW-MOLECULAR-WEIGHT[J]. Acta Pedologica Sinica,1998,35(4):493-500.

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  • 收稿日期:1997-07-12
  • 最后修改日期:1998-05-12
  • 在线发布日期: 2013-02-25
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