K+浓度对潮土和褐土钾吸附动力学的影响
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*龙怀玉在中国农业大学土壤系完成的博士论文的部分内容;国家自然科学基金“华北平原节水农业应用基础研究”(49391600)资助


K+ ADSORPTION KINETICS OF FLUVO-AQUIC AND CINNAMON SOIL UNDER DIFFERENT K+ CONCENTRATIONS
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    摘要:

    研究了潮土、褐土在五种K+浓度下吸附K+的动力学,结果表明:不同浓度下的表观吸附过程均可用一级反应动力学方程描述;表观吸附速率常数ka及其与表观平衡吸附量q的乘积与淋洗液K+浓度之间均表现为极显着的直线正相关;表观平衡吸附量与浓度之间的关系符合Langmuir或Freundlich等温吸附公式.依据试验结果对土壤钾吸附动力学进行了讨论与推导,找到四个动力学参数nk1k2qmax,通过这些动力学参数可以计算表观吸附动力学参数kaq和平衡常数K及吸附过程中的自由能变△G,在一定条件下,还可以用来判断等温吸附的类型、估算等温吸附参数.

    Abstract:

    The K+ adsorption kinetics of Fluvo-aquic soil and Cinnamon soil under different K+ concentration were studied. The results showed: (1) adsorption rate decreased with the increase in adsorption, and the relationship between them could be described with significant linear regressive equations, indicating the adsorption were fit for the first order equations; (2) the apparent adsorption rate constant ka and the product of ka multiplied by the apparent equilibrium adsorption q were significantly Sinearly correlated to K+ concentration C: (3) the relationship between q and C conformed to Langmuir and Freundlich isothermal adsorption equations. Based on those results the K+ adsorption kinetics was deduced, leading to four kinetics parameters nk1k2qmax independent of C. With nk1k2qmax the apparent parameters and free energy change △G of adsorption could be worked out, and under certain conditions nk1k2qmax could also be used to judge isothermal adsorption and reckon its parameters.

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龙怀玉,李韵珠,蒋以超. K+浓度对潮土和褐土钾吸附动力学的影响[J].土壤学报,2001,38(2):226-234. DOI:10.11766/trxb199911230211 Long Huai-yu, Li Yun-zhu, Jiang Yi-chao. K+ ADSORPTION KINETICS OF FLUVO-AQUIC AND CINNAMON SOIL UNDER DIFFERENT K+ CONCENTRATIONS[J]. Acta Pedologica Sinica,2001,38(2):226-234.

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  • 收稿日期:1999-11-23
  • 最后修改日期:2000-12-08
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  • 在线发布日期: 2013-02-25
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