土壤中14C-甲磺隆存在形态的动态研究
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*国家自然科学基金(49871044);浙江省自然科学基金(RC99032,498014);高等学校优秀青年教师教学科研奖励计划资助


DYNAMICS AND FORMS OF 14C-METSULFURON-METHYL RESIDUAL IN SOILS
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    摘要:

    利用同位素示踪技术,在实验室条件下研究了14C-甲磺隆在15种不同土壤中存在形态的动态变化.结果表明,土壤pH值与甲磺隆14C残留物的降解半衰期、残留量及可提取态残留量呈显著的正相关,而与结合态残留量呈显著负相关;土壤微生物的活性越强,甲磺隆降解速率越快,但结合态残留量也越高;土壤中各腐殖质组分和粘粒的含量也影响甲磺隆在土壤中的降解速率和存在形态.土壤中甲磺隆的残留符合一级反应动力学指数方程C=C0e-kt,拟合方程的复相关系数达到极显著水平.甲磺隆残留与土壤性质之间经逐步回归分析可得到拟合效果较好的方程,由各自变量的决定系数可知,土壤pH值、微生物生物量碳和有机碳中富啡酸碳所占的比例是影响甲磺隆在土壤中残留的主要因素.

    Abstract:

    Laboratory study on dynamics and forms of 14C-metsulfuron-methyl residual was investigated in 15 soils.It was found that there was a steady loss of 14C-metsulfuron-methyl with time in soils,which could be described by the firs-torder equation.Soil pH was positively related to the half-life,total 14C-residues and extractable 14C-residues,but negatively to the bound 14C-residues.The degradation rates and 14C-residues binding rate varied with the soil microbial biomass.The humic substances and clay could also influence the degradation rates and residual forms of 14C-metsulfuronmethyl in soils.Soil pH,microbial biomass and fulvic acid were the most significant factors controlling the degradation rates and forms of 14C-metsulfuron-methyl residual in soils.The regression equations between metsulfuron-methyl residues and soil propert ies were established after the stepwise regression analysis.

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汪海珍,徐建民,谢正苗,叶庆富.土壤中14C-甲磺隆存在形态的动态研究[J].土壤学报,2001,38(4):547-557. DOI:10.11766/trxb200101170413 Wang Hai-zhen, Xu Jian-min, Xie Zheng-miao, Ye Qing-fu. DYNAMICS AND FORMS OF 14C-METSULFURON-METHYL RESIDUAL IN SOILS[J]. Acta Pedologica Sinica,2001,38(4):547-557.

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  • 收稿日期:2001-01-17
  • 最后修改日期:2001-03-21
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  • 在线发布日期: 2013-02-25
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