扑草净和扑灭通在土壤中吸附及其与色谱热力学函数的相关性
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* 国家自然科学基金资助项目(编号39670420)


ADSORPTION OF HERBICIDE PROMETRYNE AND PROMETON ON SOILS AND CORRELATION WITH THEIR CHROMAT-OGRAPHIC THERMODYNAMICS
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    摘要:

    本研究比较了除草剂扑草净和扑灭通在6种土壤中的吸附,采用Freundlich方程对其吸附等温线进行描述,对Freundlich方程吸附常数Kaf与土壤理化性质的相关性进行了分析,由于反相高效液相色谱流动相组成与扑草净和扑灭通容量因子成线性关系,从而测定了扑草净和扑灭通的过量热力学函数ΔH,证明扑草净和扑灭通在土壤中的吸附与ΔH存在一定的关系,从而提出ΔH和ΔS可作为研究农药性质的重要参数之一。

    Abstract:

    Adsorption of prometryne and prometon on 6 kinds of soils was measured with the batch equilibration technique.It was found that adsorption isotherms could fit Freundlich equation well.The excess thermodynamic properties of the triazine in liquid chromatography were also studied.The linear relationship between the composition of the mobile phase and triazine's capacity factor was determined.The adsorption in soil showed some relationship with the excess thermodynamic properties.The excess thermodynamic properties might be considered one of the important parameters of pesticide.

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杨炜春,刘维屏,马云,刘惠君.扑草净和扑灭通在土壤中吸附及其与色谱热力学函数的相关性[J].土壤学报,2002,39(5):693-698. DOI:10.11766/trxb200011140511 Yang Wei-chun, Liu Wei-ping, Ma Yun, Liu Hui-jun. ADSORPTION OF HERBICIDE PROMETRYNE AND PROMETON ON SOILS AND CORRELATION WITH THEIR CHROMAT-OGRAPHIC THERMODYNAMICS[J]. Acta Pedologica Sinica,2002,39(5):693-698.

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  • 收稿日期:2000-11-14
  • 最后修改日期:2000-12-27
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  • 在线发布日期: 2013-02-25
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