温度对硼在三种矿物上吸附-解吸特性的影响
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* 国家自然科学基金项目(批准号:39670425)资助


EFFECTS OF TEMPERATURE ON CHARACTERISTICS OF BORON ADSORPTION-DESORPTION BY MINERALS
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    摘要:

    在实验室对天然Ca-蒙脱进行了纯化,并在一定条件下人工合成了针铁矿、水锰矿,以此作为实验材料,用吸附-解吸平衡法和反应动力学方法研究了温度对硼在Ca-蒙脱,针铁矿,水锰矿上的吸附、解吸特性的影响。结果表明:随温度升高,Ca-蒙脱对硼的吸附量升高,其对硼的解吸滞后性下降,水锰矿和针铁矿对硼的吸附量下降,其对硼的解吸滞后性加强。计算表明,在常温下,硼在Ca-蒙脱上的吸附热为63.08kJmol-1,在针铁矿和水锰矿上分别为-122.45和-93.91kJmol-1,硼在Ca-蒙脱、针铁矿和水锰矿上的解吸热分别为-31.02,53.95和46.30kJmol-1。上述结果说明,硼在Ca-蒙脱上的吸附为吸热过程,解吸为放热过程;硼在针铁矿、水锰矿上的吸附为放热过程,解吸为吸热过程。随着温度的升高,硼与矿物的初始反应速率明显加快,而整体反应速率略有下降。

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    Effects of temperature on characteristics of boron adsorption-desorption by Ca-montmorillonite, goethite and manganite were studied.The results showed that boron adsorption by Ca-montmorillonite increased with increasing temperature, whereas boron adsorption by goethite and manganite decreased as temperature rose.Boron adsorption-desorption by Ca-montmorillonite was less hysteretic as compared to goethite and manganite in terms of boron desorption rates at different temperatures.At constant temperature, boron adsorption heat for Ca-montmorillonite, goethite and manganite were 63.08, -122.45 and -93.91 kJmol-1, respective desorption heat were -31.02, 53.95 and 46.30 kJmol-1.The process of boron adsorption by Ca-montmorillonite was endothermic.By contrast, the process for goethite and manganite were exothermic.As temperature rose, boron reacted faster with minerals initially.However, the reaction rate as a whole slightly decreased.

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程东升,朱端卫,刘武定.温度对硼在三种矿物上吸附-解吸特性的影响[J].土壤学报,2002,39(6):822-829. DOI:10.11766/trxb200012210607 Cheng Dong-sheng, Zhu Duan-wei, Liu Wu-ding. EFFECTS OF TEMPERATURE ON CHARACTERISTICS OF BORON ADSORPTION-DESORPTION BY MINERALS[J]. Acta Pedologica Sinica,2002,39(6):822-829.

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  • 收稿日期:2000-12-21
  • 最后修改日期:2001-07-08
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  • 在线发布日期: 2013-02-25
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