恒电荷土壤及可变电荷土壤与离子间相互作用的研究Ⅲ Cu2+和Zn2+的吸附特征
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国家自然科学基金项目(49831005);国家重点基础研究发展规划项目(973课题2002CB410809)资助


INTERACTION OF IONS WITH CONSTANT CHARGE SOILS AND VARIABLE CHARGE SOILS Ⅲ. CHARACTERISTICS OF Cu2+ AND Zn2+ ADSORPTION IN SINGLE AND CO-EXISTING SYSTEMS
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    摘要:

    研究了3种典型可变电荷土壤和4种典型恒电荷土壤在不同pH和不同浓度下单纯及共存体系中Cu2+和Zn2+的吸附及其影响因素.结果表明,两类土壤对Cu2+或Zn2+的吸附量均随平衡浓度增加而增大,符合Langmuir吸附等温式;当Cu2+、Zn2+浓度一定时,pH升高使Cu2+、Zn2+吸附量增大,但当pH>5时,Cu2+、Zn2+吸附量随pH变化甚微,出现一个接近最大吸附量的“平台”.当添加Cu2+、Zn2+浓度相同,但二种离子的总浓度不同时,平衡液的Cu2+/Zn2+浓度比均小于1,说明两类土壤对Cu2+的吸附选择性大于Zn2+,且这种趋势不因pH和离子浓度而改变.当Cu2+、Zn2+共存时,使可变电荷土壤的Zn2+吸附量减小约70%,是恒电荷土壤降低量的约1.5倍;可变电荷土壤吸附一个Cu2+或Zn2+时所释放H+的平均数,明显大于恒电荷土壤者,说明可变电荷土壤对Cu2+及Zn2+的吸附中专性吸附的比例较恒电荷土壤大.

    Abstract:

    Adsorptions of Cu2+ and Zn2+ by three typical variable charge soils and four typical constant charge soils di-f ferent in pH and in accompanying ion, Na+, Zn2+ or Cu2+ were determined, respectively. The results showed that adsorption of Cu2+ and Zn2+ by the soils could be described by the Langmiur equation C/(Xm) = 1/Kb+C/b both in the single ion and coexisting ions systems. The adsorption of Cu2+ or Zn2+ increased with pH and reached a plateau value when the pH value was 5. The affinity in adsorption of Cu2+ was greater than that of Zn2+. The mechanism of adsorption Cu2+ and Zn2+ was closely related to chemical composition and surface properties of the soils. The relative contribution of specific adsorption to the adsorption of Cu2+ and Zn2+ by the variable charge soils was greater than that by the constant charge soils.

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徐明岗,季国亮.恒电荷土壤及可变电荷土壤与离子间相互作用的研究Ⅲ Cu2+和Zn2+的吸附特征[J].土壤学报,2005,42(2):225-231. DOI:10.11766/trxb200405240208 Xu Minggang, Ji Guoliang. INTERACTION OF IONS WITH CONSTANT CHARGE SOILS AND VARIABLE CHARGE SOILS Ⅲ. CHARACTERISTICS OF Cu2+ AND Zn2+ ADSORPTION IN SINGLE AND CO-EXISTING SYSTEMS[J]. Acta Pedologica Sinica,2005,42(2):225-231.

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  • 收稿日期:2004-05-24
  • 最后修改日期:2004-07-16
  • 在线发布日期: 2013-02-25
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