不同pH下有机酸对针铁矿和膨润土吸附Cd2+、Pb2+的影响
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*国家自然科学基金项目(No.40371065);湖北省自然科学基金(No.2005ABA139)资助


EFFECTS OF ORGANIC ACIDS ON Cd2+ AND Pb2+ ADSORPTION ON GOETHITE AND BENTONITE AT DIFFERENT pH
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    摘要:

    用平衡吸附法研究了不同pH下,三种有机酸(乙酸、酒石酸和柠檬酸)对针铁矿和膨润土等温吸附Cd2+、Pb2+的影响.结果表明:在加入的Cd2+、Pb2+浓度分别小于0.2mmolL-1和4.0mmolL-1时,针铁矿和膨润土吸附平衡体系的pH随加入重金属浓度的增加而降低,膨润土体系的pH降低更明显.在有机酸作用下,pH对针铁矿和膨润土吸附Cd2+、Pb2+的影响差异显著.3<pH<4.5时,针铁矿Cd2+的吸附率很小;4.5<pH<8时,Cd2+吸附率明显上升,并趋向饱和吸附.针铁矿Pb2+的吸附率从pH3时开始上升,pH5.5时其吸附率基本稳定于95%.三种有机酸作用下,膨润土Cd2+的吸附率均从40%(pH3时)缓慢地上升;pH8时吸附率近90%.pH3时,加入各有机酸的膨润土Pb2+吸附率均在60%左右;pH6时,加入柠檬酸的上升至80%,其他处理均上升至95%.不同pH下,膨润土Cd2+、Pb2+吸附率的变幅为40%~90%,而针铁矿的为3%~90%;有机酸对促进针铁矿吸附Cd2+和Pb2+的影响大小顺序均为:柠檬酸>酒石酸>乙酸,其对膨润土吸附的影响差异不明显.

    Abstract:

    Effects of organic acids (acetic acid,tartaric acid and citric acid) on Cd2+ and Pb2+ adsorption on goethite and bentonite were studied with the batch method.Results show that pH decreased with the increase in concentration of Cd2+ and Pb2+ in the goethite and bentonite isothermal systems when the concentration of Cd2+ and Pb2+ was lower than 0.2 mmol L-1 and 4.0 mmol L-1,respectively.The decrease of pH in bentonite system was more obvious than in goethite system.The effect of pH on Cdand Pbadsorption of goethite and bentonite varied sharply with organic acids added.Cd2+ sorption rate was small with goethite when pH was in the range from 3 to 4.5,but it went upward sharply when pH was higher (4152+ sorption rate began to increase when pH was 3 with goethite,and it leveled off to 95% at pH 5.5.Affected by three organic acids,Cd2+ sorption rate increased slowly from 40% at pH 3 with bentonite,and approached close to 90% at pH 8.Pb2+ sorption rates were around 60% in bentonite systems added with different organic acid.They increased to 80% when citric acid was added and 95% when other organic acid added.Cd2+ and Pb2+ sorption rates varied from 40% to 90% with bentonite at different pH,but from 3% to 90% with goethite.In terms of effect of organic acids on Cd2+ and Pb2+ adsorption of goethite,the three acids were in the order of citric acid > tartaric acid > acetic acid,but the effect was not clear with bentonite.

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黄丽,刘畅,胡红青,刘凡,李学垣.不同pH下有机酸对针铁矿和膨润土吸附Cd2+、Pb2+的影响[J].土壤学报,2007,44(4):643-649. DOI:10.11766/trxb200601230409 Huang Li, Liu Chang, Hu Hongqing, Liu Fan, Li Xueyuan. EFFECTS OF ORGANIC ACIDS ON Cd2+ AND Pb2+ ADSORPTION ON GOETHITE AND BENTONITE AT DIFFERENT pH[J]. Acta Pedologica Sinica,2007,44(4):643-649.

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  • 收稿日期:2006-01-23
  • 最后修改日期:2006-06-26
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  • 在线发布日期: 2013-02-25
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