一个改进的土壤铵、磷和钾等温吸附新模型
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国际植物营养研究所(IPNI, Fujian13)和福建省财政专项基金(Y015)资助


A modified isothermal adsorption model for NH4+, PO43- and K+ sorption in soil
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    摘要:

    土壤对养分的吸附特性是土壤化学和植物营养学的重要研究内容。9个供试土壤的NH4+、PO43-和K+吸附试验表明,Langmuir、Freundlish和Temkin等温吸附方程对其有较好的拟合效果,但亦有部分供试土壤的拟合精度不良。本文引进种群生态学的“形状因子d”概念,在Langmuir方程基础上构造了一个新的吸附模型。理论分析表明,新吸附模型综合反映了3个等温吸附方程所描述的吸附特征。模拟结果表明,等温吸附方程模拟不佳的供试土壤,用新模型模拟均能达到显著水平;新吸附模型的拟合精度(R2)高于3个等温吸附方程,且标准差最小。形状因子d的变化幅度在0.608 0~2.929 0,体现了土壤理化性质对NH4+、PO43-和K+等温吸附曲线形状的影响。新吸附模型和Langmuir方程的NH4+、PO43-和K+的qm值之间的线性相关系数分别为0851 5**、0.825 8**和0.912 8**(n=9)。土壤理化性质分析表明,新吸附模型的PO43-和K+的qm值与土壤有机质之间、土壤NH4+和K+的qm值与CEC之间均有显著水平的线性正相关。NH4+的qm值与土壤碱解氮含量亦呈显著水平的线性正相关,而PO43-的qm值与土壤有效磷含量则呈显著水平的线性负相关。数学形式简洁的新等温吸附模型为采用统一模式定量处理土壤对NH4+、PO43-和K+的吸附特性提供了一条新途径。

    Abstract:

    Nutrient adsorption characteristics of soil are important issues in the study of soil chemistry and plant nutrition. An experiment was carried out on NH4+, PO43- and K+ adsorption in 9 soils. Results show that Langmuir, Freundlish and Temkin isothermal adsorption equations described the sorptions quite well, but they were not perfect. A concept of “shape factor d ” of genecology was introduced to create a new adsorption model based on the Langmuir equation. Theoretical analysis indicates that the new adsorption model reflected comprehensively dynamic characteristics of the three isothermal adsorption equations. Simulation results show that the soils which the three isothermal adsorption equations didn’t fit well, were well described by the new model. The new model was higher in simulation precision (R2) and lower in standard deviation than the three isothermal adsorption equations. Its shape factor “d ” varied between 0.608 0~2.929 0, demonstrating effect of physical-chemical properties of the soils on shapes of NH4+, PO43- and K+isothermal adsorption curves. The linear correlation coefficient between the new model and Langmuir equation inqm values of NH4+ and PO43- and K+ was 0.851 5**, 0.825 8** and 0.912 8** (n=9) respectively. According to the new adsorption model, soil physicalchemical analysis show significantly positive linear correlation between qm values of PO43- or K+ calculated by the new model and soil organic matter content, between qm values of NH4+ or K+ and CEC, and between qm value of NH4+ and soil available nitrogen as well, but significantly negative correlation between qmvalue of PO43- and available phosphorus in the soil. The new adsorption model, concise in mathematical form, provides a new approach to using a uniform model for quantification of NH4+, PO43- and K+ adsorption characteristics in soil.

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颜明娟,章明清,陈防,林琼,陈子聪,李娟.一个改进的土壤铵、磷和钾等温吸附新模型[J].土壤学报,2010,47(3):458-464. DOI:10.11766/trxb200803190310 Yan Mingjuan, Zhang Mingqing, Chen Fang, Lin Qiong, Chen Zhichong, Li Juan. A modified isothermal adsorption model for NH4+, PO43- and K+ sorption in soil[J]. Acta Pedologica Sinica,2010,47(3):458-464.

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