梯度扩散薄膜评估土壤重金属生态风险的发展现状及应用前景
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作者单位:

1.北京工业大学环境科学与工程学院;2.中国水利水电科学研究院

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国家自然科学基金项目(52200223)和北京市教育委科技一般项目基金(KM202310005018)资助


Review and Prospects for Ecological Risk Assessments of Soil Heavy Metals Using Diffusive Gradient in Thin-Films Technology
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Affiliation:

1.Beijing University of Technology;2.China Academy of Water Resources and Hydropower Research

Fund Project:

Supported by the National Natural Science Foundation of China (No. 52200223) and the Municipal Education Commission Science and Technology General Project Fund of Beijing, China (No. KM202310005018)

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    摘要:

    人类生产活动的广泛开展和经济社会的快速发展,导致土壤中重金属含量大幅上升,严重影响生态环境质量、威胁人体健康安全,因此亟需对土壤重金属生态风险进行精准评价。传统风险评价技术仅关注土壤重金属的总量数据,而缺少形态变化和生物有效含量信息。近年来,梯度扩散薄膜技术(DGT)以原位采集、低环境干扰和应用稳定等特点被广泛用于土壤重金属生态风险研究。该技术基于菲克第一定律,通过对目标污染物梯度扩散及其缓冲动力学过程的研究,获得其在实际环境中的形态变化及生物有效含量水平,并发展出以该技术为核心的DGT诱导土壤/沉积物通量模型(DIFS)工具。鉴于此,本文首先针对土壤重金属污染的严重性和迫切性为出发点,阐述DGT作为精准评估工具的技术特点和应用必要性,根据国内外研究现状提出影响土壤重金属风险的主要环境因素,并通过DIFS模型直观揭示土壤功能异同条件下土壤重金属微观动力学以及相应的生态风险差异,最后围绕DGT技术评价生态风险的未来发展和研究方向提出建议。

    Abstract:

    Extensive human activities, including industrialization, intensive agriculture, and urban construction, coupled with the accelerated pace of socio-economic development, have significantly precipitated and caused a measurable surge in heavy metal concentrations in soil environments. This environmental issue severely degrades the quality of natural environments, thereby engendering substantial threats to human health and ecological safety. Conventional risk assessment techniques have focused on quantifying the total content of heavy metals in soils. However, such approaches are inherently limited to capturing critical insights into speciation changes and bioavailable concentrations, which are essential for accurate ecological risk assessment of heavy metals. In recent years, the diffusive gradients in thin-films (DGT) technique has emerged as an innovative and promising tool for in-situ measurement of heavy metals in soils. DGT is recognized for its stable performance with minimal disturbance to the surrounding natural environment in real-world applications. Based on Fick"s first law, the DGT technique facilitates the analysis of gradient diffusion and buffering kinetics of target pollutants, thereby providing valuable data on their speciation and bioavailability in diverse environmental settings. Furthermore, the integration of the DGT technique with the DGT-induced fluxes in soil/sediments (DIFS) model significantly enhances its applicability, enabling detailed investigations into the dynamic behaviors of heavy metals within soil matrices. This study provides a comprehensive review of the current advancements and prospects of utilizing the DGT technique for soil heavy metal risk assessments. By examining the severity and urgency of heavy metal contamination in soils, the technical advantages of DGT as a precise assessment tool are delineated, and the necessity of its application is emphasized. Through a critical analysis, the principal environmental factors influencing the ecological risks associated with soil heavy metals are identified, including soil composition, pollutant characteristics, and external environmental conditions. Additionally, this study provides an in-depth overview of the DIFS model"s role in visualizing the minute-scale dynamic behaviors of heavy metals under varying soil functional scenarios, highlighting the differences in ecological risks that may arise. In the concluding section, strategic recommendations for advancing DGT applications are outlined, focusing on improving the analytical criteria, enhancing the preparation of binding layer materials, facilitating multi-contaminant enrichment, and integrating multiple analytical techniques. These improvements are crucial for advancing the detection and quantification of heavy metals in complex environmental media. Potential directions for future research are also discussed to further expand the capabilities of DGT and DIFS in the context of soil pollution monitoring and ecological risk assessment.

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李丹阳,李寒冰,陈博,赵晓辉,梁艺萱,陈莎.梯度扩散薄膜评估土壤重金属生态风险的发展现状及应用前景[J].土壤学报,2026,63(1). DOI:10.11766/trxb202411140439 LI Danyang, LI Hanbing, CHEN Bo, ZHAO Xiaohui, LIANG Yixuan, CHEN Sha. Review and Prospects for Ecological Risk Assessments of Soil Heavy Metals Using Diffusive Gradient in Thin-Films Technology[J]. Acta Pedologica Sinica,2026,63(1).

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  • 收稿日期:2024-11-14
  • 最后修改日期:2025-06-26
  • 录用日期:2025-07-17
  • 在线发布日期: 2025-07-18
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