市售酸性土壤调理剂的信息统计与性质分析
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1.西南大学 资源环境学院;2.重庆市南川区农业技术推广中心;3.重庆市农业技术推广总站

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国家自然科学基金项目(41701256)和西南大学本科生创新基金项目(202110635097)资助


Information Statistics and Property Analysis of Commercially Acidic Soil Amendments
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Affiliation:

1.College of Resources and Environment,Southwest University;2.Agricultural Technology Extension Station of Nanchuan District;3.Chongqing General Agricultural Technology Extension Station

Fund Project:

Supported by the National Natural Science Foundation of China (No. 41701256) and the Undergraduate Innovation Fund of Southwest University(No. 202110635097)

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    摘要:

    直接施用调理剂是改良酸性土壤的重要方法。为了深入了解我国市售酸性土壤调理剂的性质特征,本研究对我国酸性土壤调理剂的产品登记情况和发明专利申请信息进行了系统整理与分析,并针对24种市售酸性土壤调理剂包装上标注的形态特征和主要有效成分进行了测定、匹配和验证。通过X射线衍射(XRD)和傅里叶变换红外光谱(FTIR)分析,进一步明确了这些商品化酸性土壤调理剂的主要化学组分。结果显示,我国酸性土壤调理剂产品种类丰富,在各类土壤调理剂中占比高达78%。受市场需求、原料产地以及农业发展特点等因素影响,酸性土壤调理剂的生产厂商主要集中于广东和山东地区。我国酸性土壤调理剂产品的发明专利授权率较低,不足10%,其中已授权专利所涉及的原材料以有机物料和工农业副产品为主,天然矿物和化工产品次之。在产品登记信息中,碳酸盐矿物和牡蛎壳是最常用的原材料。与专利申请相比,实际生产中选择的原材料更加廉价且易获取。我国酸性土壤调理剂的形态主要包括粉剂和颗粒态,其产品登记比例约为2:1。pH、CaO和MgO三个碱度指标是衡量酸性土壤调理剂改善土壤酸度及补充盐基养分效果的关键参数。然而,部分商品化酸性土壤调理剂在包装上未完全标明这三项重要参数。通过对24种市售酸性土壤调理剂的测定发现,所有样品均具有较高的pH和CaO含量,大部分产品还含有少量MgO,绝大多数调理剂产品的碱度测定值与其标明值或标明范围相符。XRD和FTIR分析结果表明,我国市售酸性土壤调理剂的主要成分为CaCO₃。此外,因原材料和加工工艺的不同,部分产品还含有Ca(OH)₂、CaO、CaMg(CO₃)₂、MgO等快速调节土壤酸度的碱性物质。除上述碱性物质外,大多数酸性土壤调理剂中还含有硅酸盐矿物或SiO₂等含硅物质。综上所述,当前我国酸性土壤调理剂的主要功能集中于调节土壤酸度。然而,由于产品功能较为单一,市场推广面临一定挑战。为满足农业生产多样化的实际需求,亟需进一步研发既能调节土壤酸度,又兼具培肥功能的多功效调理剂产品,以提升产品实用性和市场竞争力。此外,酸化土壤改良是一项系统工程。除了加强新产品的研发,还需同步推进土壤酸化监测与预警、酸化土壤改良技术与模式集成等相关工作,从而切实推动我国酸性耕地的改良进程及其可持续利用。

    Abstract:

    【Objective】Direct application of soil amendments represents a crucial approach for ameliorating acidic soils. Grasping the fundamental properties of commercially available acidic soil amendments is vital for developing strategies to improve acidic soils in China. 【Method】In this study, detailed information regarding product registration and patent applications for acidic soil amendments in China was gathered and systematically organized. Subsequently, the basic properties; including particle size distribution, pH, contents of CaO and MgO, crystalline minerals, and functional groups, of 24 randomly selected commercial soil amendments were determined. The crystalline minerals and functional groups of soil amendments were identified by X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR) analyses. 【Result】The results indicate that a substantial number of acidic soil amendments exist in China, accounting for 78% of all types of soil amendments. Driven by market demand, raw material availability, and agricultural development characteristics, the manufacturers of acidic soil amendments are predominantly located in Guangdong and Shandong provinces. The authorization rate of patents for acidic soil amendments in China is less than 10%. Among the authorized patents, the primary raw materials are organic matter and by-products from industry and agriculture, followed by natural minerals and chemical products. Specifically, the main raw materials listed in product registrations were carbonate minerals and oyster shells and most of the amendments were available in powder and granular forms, with a product registration ratio of approximately 2:1. However, the adoption of the powder products face challenges in promotion due to dust generation during application. The pH value, CaO content, and MgO content are the core indicators that most effectively reflect the ability of acidic soil amendments to mitigate soil acidity and replenish soil base nutrients. Even though some of the soil amendments did not fully disclose these three parameters on their packaging, the experimental evidence indicated that they were highly alkaline and exhibited high pH values and CaO contents, and most products also contained small amounts of MgO. These measured indicators aligned with their labeled values or ranges and the XRD and FTIR analyses further demonstrated that the predominant component in the commercially available amendments was CaCO₃. In addition, other alkaline constituents such as Ca(OH)₂, CaO, CaMg(CO₃)₂, and MgO were also present in some of the soil amendments, depending on their raw materials and production technologies. Moreover, most of the amendments also contained silicate minerals or SiO₂. 【Conclusion】The results of this study revealed that the primary function of the commercially available amendments for acidic soils in China is the amelioration of soil acidity. However, due to the single functionality of these products, there are significant challenges in market promotion. To meet the diversified needs of agricultural production, it is necessary to further develop multi-functional acidic soil amendment products that can both regulate soil acidity and enhance soil fertility, thereby improving product practicability and market competitiveness. In addition, acidified soil amelioration is a systematic project. Besides strengthening the development of new products, it is also necessary to simultaneously advance various aspects of work such as soil acidification monitoring and early warning, and integration of acidified soil improvement technologies and models, in order to effectively promote the improvement and sustainable utilization of China""s acidic cultivated land.

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于俊峰,郭心怡,李忠意,付登伟,王远鹏,周 佳,王 帅.市售酸性土壤调理剂的信息统计与性质分析[J].土壤学报,DOI:10.11766/trxb202503290145,[待发表]
YU Junfeng, Guo Xinyi, LI Zhongyi, Fu Dengwei, WANG Yuanpeng, ZHOU Jia, WANG Shuai. Information Statistics and Property Analysis of Commercially Acidic Soil Amendments[J]. Acta Pedologica Sinica, DOI:10.11766/trxb202503290145,[In Press]

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  • 收稿日期:2025-03-29
  • 最后修改日期:2025-06-21
  • 录用日期:2025-07-31
  • 在线发布日期: 2025-08-25
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