干旱区煤矿周缘重金属污染土壤的环境磁学特征及污染源解析
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干旱区生态安全与可持续发展全国重点实验室

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新疆维吾尔自治区自然科学基金杰出青年科学基金项目(2024D01E34)、新疆人才发展基金项目(XJRC-2025-KJ-PY-KJLJ-085)、国家自然科学基金项目(42474100)共同资助


Environmental Magnetic Characteristics and Source Apportionment of Heavy Metal Contaminated Soils Surrounding Coal Mines in Arid Regions
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State Key Laboratory of Ecological Safety and Sustainable Development in Arid Lands, Xinjiang Institute of Ecology and Geography, Chinese Academy of Sciences

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Supported by the Natural Science Fund for Distinguished Young Scholars of Xinjiang Uygur Autonomous Region, China (No. 2024D01E34), the Talent Development Fund of Xinjiang Uygur Autonomous Region, China (No. XJRC-2025-KJ-PY-KJLJ-085), and the National Natural Science Foundation of China (No. 42474100)

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    摘要:

    环境磁学方法已被广泛应用于土壤重金属污染的快速识别与溯源研究中,但传统的简单相关性分析难以揭示磁学参数与重金属之间的驱动方向和因果机制,尤其是在污染来源复杂、输入途径多样的矿区周缘地区。以新疆吐鲁番七泉湖某煤矿周缘土壤为研究对象,针对锌(Zn)、铅(Pb)、砷(As)、镍(Ni)、铬(Cr)和铁(Fe)等重金属,通过耦合环境磁学指标(磁化率(χ)、饱和等温剩磁(SIRM)、非磁滞剩磁(χARM)、χARM/SIRM、χARM/χ)、绝对主成分得分-多元线性回归(APCS-MLR)源解析模型与地理收敛交叉映射(GCCM)模型,旨在识别重金属来源,揭示其与磁学参数间的因果驱动机制。结果表明,研究区内土壤重金属污染具有显著的多源叠加特征。其中,Pb、Zn和Fe主要受近源冶炼活动影响,表现为近工业区磁化率明显增强;As和Ni则与煤矿开采及运输过程中产生的细粒磁性颗粒输入密切相关,对 χARM及其比值参数具有显著响应;Cr的异常富集主要来源于固废堆积的作用。基于 GCCM 模型的因果驱动分析进一步明确了不同磁学参数对各类污染源的响应差异及作用方向,有助于降低单纯相关性分析可能带来的误判风险。研究结果系统揭示了干旱区煤矿周缘土壤重金属污染的环境磁学响应特征及其来源机制,为复合污染区的环境管理与风险防控提供了科学支撑。

    Abstract:

    【Objective】Soil heavy metal contamination in mining areas has become an important environmental concern, particularly in arid regions where fragile ecosystems and intensive anthropogenic activities accelerate pollutant accumulation. While environmental magnetism has emerged as a cost-effective proxy for monitoring heavy metals, conventional statistical methods, such as simple correlation analysis, often fail to decipher the complex driving directions and causal mechanisms between magnetic parameters and pollutants. This is especially severe in areas with heterogeneous emission sources. Therefore, this study aimed to characterize the spatial distribution of heavy metals (Zn, Pb, As, Ni, Cr, and Fe) and to elucidate their causal linkages with magnetic mineralogical proxies.【Method】This study focuses on the Qiquanhu coal-mining area in the Turpan Basin, Xinjiang, China. A total of 330 soil samples were collected from 165 sites at two depths (0–10 cm and 10–20 cm) across the study area. Magnetic susceptibility (χ), saturation isothermal remanent magnetization (SIRM), and anhysteretic remanent magnetization (ARM) were measured, alongside the calculation of grain-size- dependent ratios (χARM/χ and χARM/SIRM). The concentrations of six heavy metals were determined using inductively coupled plasma mass spectrometry (ICP–MS). To quantitatively apportion pollution sources, the absolute principal component scores–multiple linear regression (APCS–MLR) receptor model was employed. The geographical convergent cross mapping (GCCM) method was utilized to identify the bidirectional causal relationships and driving strengths between magnetic parameters and heavy metal concentrations based, overcoming the limitations of traditional linear correlation.【Result】The results demonstrated that heavy metal enrichment in the study area was characterized by distinct multi-source superposition. The concentrations of Pb, Zn, and Fe were significantly higher in proximity to industrial facilities, showing a strong coupling with magnetic concentration-dependent parameters (χ, SIRM, and χARM). This suggested that high-temperature smelting activities released coarse-grained magnetic spherules that co-precipitated with these metals. In contrast, As and Ni were primarily associated with fine-grained magnetic particles generated during coal mining and transportation, exhibiting a sensitive response to χARM/χ and χARM/SIRM. However, Cr enrichment showed localized heterogeneity, primarily linked to the accumulation of mining solid waste. The APCS–MLR model identified three primary pollution factors accounting for 86.2% of the total variance, representing industrial smelting, coal-related activities, and lithogenic/waste sources, respectively. GCCM analysis further confirmed that magnetic concentration parameters exerted a strong causal drive on Pb and Zn, while grain-size-sensitive ratios served as robust causal indicators for As and Ni, effectively reducing the risk of misinterpretation inherent in simple correlation.【Conclusion】This study confirms that environmental magnetic parameters can effectively fingerprint the source-specific distribution of heavy metals in arid coal-mining soils. The integration of environmental magnetism, APCS–MLR source apportionment, and GCCM causal analysis provides an advanced diagnostic framework for pollution identification. These findings offer critical scientific evidence for targeted environmental management, risk mitigation, and the development of magnetic-based monitoring protocols in complex polymetallic contaminated regions.

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林湛伟,乔庆庆,李刚强,汪冬,陈宇东,高仲寅.干旱区煤矿周缘重金属污染土壤的环境磁学特征及污染源解析[J].土壤学报,DOI:10.11766/trxb202512220609,[待发表]
LIN Zhanwei, QIAO Qingqing, LI Gangqiang, WANG Dong, CHEN Yudong, GAO Zhongyin. Environmental Magnetic Characteristics and Source Apportionment of Heavy Metal Contaminated Soils Surrounding Coal Mines in Arid Regions[J]. Acta Pedologica Sinica, DOI:10.11766/trxb202512220609,[In Press]

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  • 收稿日期:2025-12-22
  • 最后修改日期:2026-05-31
  • 录用日期:2026-08-25
  • 在线发布日期: 2026-08-31
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