磷石膏生态化利用与成土驱动技术路径思考
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作者单位:

1.中南大学冶金与环境学院;2.中南大学矿冶场地生态修复研究中心;3.贵州大学资源与环境工程学院

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国家自然科学基金区域创新重点项目(U24A20636)和湖南省自然科学基金创新研究群体项目(2024JJ1012)


Perspectives on the ecological utilization of phosphogypsum and technical pathways for constructed technosols
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Affiliation:

1.Central South University;2.Guizhou University

Fund Project:

National Natural Science Foundation of China (No. U24A20636) and the Natural Science Foundation of Hunan Province, China (No. 2024JJ1012)

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    摘要:

    磷石膏是湿法磷酸工艺产生的工业副产物,全球有效利用率约14%,累积堆存量60亿吨,并以每年2亿吨的速度增加,迄今尚无经济可行的规模化利用方法,磷石膏堆存的环境问题正严重威胁磷化工行业的可持续发展。基于Web of Science核心数据库2006–2026年文献计量分析,本文系统总结磷石膏生态化利用研究进展,分析磷石膏存在酸性胁迫、化学组分复杂、结构稳定性差等成土障碍;通过对比磷石膏与土壤的性质差异,提出多元固废协同磷石膏人工成土的技术思路。通过化学性质调控(无害化)、物理性质改善(结构化)、生态过程驱动(功能化),逐步形成环境风险可控、基质结构稳定、生态功能良好的人工土壤,实现磷石膏生态化处置与规模化消纳的协同目标。围绕酸性调控与磷氟固定、矿物组成及物理结构改善、养分配比优化与生物定殖等关键环节展开分析,未来应加强成土驱动机制、生态安全边界及多元固废协同调控研究,构建稳定、高效、可复制推广的磷石膏生态化处置体系,为磷石膏土壤化利用及人工土壤技术研发提供新思路。

    Abstract:

    Phosphogypsum (PG) is an industrial by product generated from wet process phosphoric acid production, with both resource potential and environmental risks. Restricted by its huge output and limited resource utilization pathways, its large scale consumption remains challenging, which seriously hinders the green and sustainable development of China’s phosphorus chemical industry. Based on the bibliometric analysis of relevant publications from the Web of Science Core Collection spanning 2006 2026, this paper systematically reviews the generation, stockpiling and weathering processes of PG, and summarizes the research advances in its ecological utilization. Key obstacles including acid environmental stress, complex impurity components, insufficient structural stability, imbalanced nutrient supply and constrained biological processes are analyzed. By comparing the properties of PG with natural soils, a multi process coupled pedogenic driven research idea for transforming PG into constructed technosols is proposed from the perspective of ecological utilization. That is, hazard free treatment via chemical property regulation, structural improvement through physical property optimization, and functional development driven by biological processes. An artificial soil matrix with controllable environmental risks, stable substrate structure and sound ecological functions can be gradually established to achieve the synergistic goals of ecological disposal and large scale consumption of PG. This paper discusses relevant mechanisms from the aspects of acid base regulation, phosphorus fluorine stabilization, particle mineral and pore structure reconstruction, nutrient regulation and biological colonization. It is considered that soil like utilization of PG still faces challenges such as long term risk prevention and control, long term maintenance of substrate functions and large scale engineering application. Future studies should strengthen research on pedogenic driving mechanisms, ecological safety thresholds and multi solid waste synergistic regulation mechanisms, so as to establish a stable, efficient and replicable technical system for ecological utilization of PG and provide new insights for its large scale consumption.

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薛生国,赵婉怡,李瑞,刘燚,杨泽通,王立萍,邹昊,陈振山,吴攀.磷石膏生态化利用与成土驱动技术路径思考[J].土壤学报,DOI:10.11766/trxb202606100298,[待发表]
Xue Shengguo, Zhao Wanyi, Li Rui, Liu Yi, Yang Zetong, Wang Liping, Zou Hao, Chen Zhenshan, Wu Pan. Perspectives on the ecological utilization of phosphogypsum and technical pathways for constructed technosols[J]. Acta Pedologica Sinica, DOI:10.11766/trxb202606100298,[In Press]

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  • 收稿日期:2026-06-10
  • 最后修改日期:2026-10-15
  • 录用日期:2026-10-23
  • 在线发布日期: 2026-10-23
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