用四苯硼测定土壤中水溶性钾Ⅰ.银量法和溴酸盐法
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DETERMINATION OF WATER SOLUBLE POTASSIUM IN SOILS BY TETRAPHENYLBORON Ⅰ. ARGENTOMETRIC AND BROMATOMETRIC METHODS
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    摘要:

    侧定钾的常用方法(例如亚稍酸钻纳法、高氯酸法、氯铂酸法、六稍基二苯胺法等)的一般缺点县沉浪的成分不恒定。灵敏性低.操作手续冗长。自从G.Wittia等[1]提出用四苯硼(TPB)作为钾的试剂的可能性以后,1951年P. Raff等[2]即用于钾的重量法测定。

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    The present paper deals with the investigation on the argentometric and bromatometric methods for the determination of water soluble potassium with TPB (tetraphenylboron) in saline soils. Modifications of these methods are recommended.In the argentometric titration, the writer recommends the use of fluorescein as an adsorption indicator which gives a better color contrast of yellowish green fluorescence to pink. In addition, this method is comparatively simple and inexpensive.In the bromatometric method instead of the sintered glass filter an ordinary retentive, quantitative filter paper has been found adoptable in filtering the K-TPB precipitate. The bromatometric method, though comoarativelv tedious. gives a higher degree of accuracy and precision than the argentometric method.

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李酉开.用四苯硼测定土壤中水溶性钾Ⅰ.银量法和溴酸盐法[J].土壤学报,1964,12(1):83-90. Y. K. LI. DETERMINATION OF WATER SOLUBLE POTASSIUM IN SOILS BY TETRAPHENYLBORON Ⅰ. ARGENTOMETRIC AND BROMATOMETRIC METHODS[J]. Acta Pedologica Sinica,1964,12(1):83-90.

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  • 在线发布日期: 2013-02-25
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