土壤电化学性质的研究--Ⅶ.土壤中氯化钠的平均活度的田间测定
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STUDIES ON ELECTROCHEMICAL PROPERTIES OF SOILS.Ⅶ.POTENTIOMETRIC DETERMINATION OF THE MEAN ACTIVITY OF NaCl IN SOILS IN SITU
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    摘要:

    氯化钠是盐渍化土壤中可溶性盐的一个重要组成分,对土壤性质和植物生长有直接影响。为了测定土壤中的氯化钠含量,通常采用一定的水土比例将盐溶出,然后用化学法或电化学法测定两种离子。但是在关于土壤盐分与植物生长的关系的研究中,较为关心的是植物根系所处的实际土壤环境。如果能够不将土壤取出而直接原位测定该种条件下的离子状况,应该具有重要意义。近年来离子选择性电极的发展,使这种测定成为可能。

    Abstract:

    A potentiometric method for the determination of the apparent mean activity of NaCI in saline soils in situ was proposed. A spear-type sodium-selective glass electrode and a spear-type chloride-selective pressed electrode were used. It was found that under ordinary circumstances the equilibrium potential between the electrodes and the soil generally reached within 10 min. after the insertion of the electrode into the soil, the actual time being dependent on the water content and NaCI content of the soil. For most saline soils with a water content near field capacity, the equilibrium time was 2-5 minutes. Prolonged usage may affect the function of the electrodes due to the adhesion of soil colloidal particles on the surface of the chloride-selective electrode and the dehyciration of the sodium-selective electrode. These affects may be avoided by frequent rubbing with fine emery paper and rinsing with water respectively.

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张道明,张效年,李成保,吴汮,于天仁.土壤电化学性质的研究--Ⅶ.土壤中氯化钠的平均活度的田间测定[J].土壤学报,1979,16(4):362-371. Zhang Dao-ming, Zhang Xiao-nian, Li Cheng-bao, Wu Jun, Yu Tian-ren. STUDIES ON ELECTROCHEMICAL PROPERTIES OF SOILS.Ⅶ. POTENTIOMETRIC DETERMINATION OF THE MEAN ACTIVITY OF NaCl IN SOILS IN SITU[J]. Acta Pedologica Sinica,1979,16(4):362-371.

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  • 在线发布日期: 2013-02-25
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