磷酸盐在白浆土中的吸附与解吸特性
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CHARACTERISTICS OF PHOSPHATE ADSORPTION AND DESORPTION IN ALBIC SOILS
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    摘要:

    本文对采自黑龙江省三江平原地区三个不同亚类的四种白浆土的表层和白浆层的磷酸盐吸附与解吸特性做了较详细的研究,结果表明,白浆土是一种吸磷能力很强的土类。整个吸附过程分快反应和慢反应两步进行。吸附动力学过程能很好地拟合Laogmuir型方程。磷在白浆土中的吸附特性表明,土壤中存在两种能量不同的吸附点位,因此,其吸附过程可用双面Langmuir方程描述。白浆土的解吸过程存在明显的滞后现象,连续解吸特征进一步证明白浆土中含有两种不同类型的吸附点位或吸附区域。一类结合能常数较高,被吸附的磷难于解吸,另一类则相反。有机质显著地影响白浆土对磷的吸附与解吸。增加或去除有机质都可促进磷的吸附,但增加有机质可使被吸附的磷易于解吸,在低磷浓度下尤其如此,而去除有机质后,则使磷的解吸难于进行。

    Abstract:

    The characteristics of phosphate(P) adsorption and desorption by 4 albic soils collected from the Three-River Plain.The experimental results showed that the soils had very strong ability to adsorb P.The whole process of adsorption was divided into the initially fast reaction (within 24 hours) and the slow reaction thereof ter.In all kinetic models examined in this study, the Langmuir-type equation most perfectly modeled the kinetic processes of P sorption.The properties of P adsorption suggested that there were two populations of adsorbed sites which differed in the affinity for P,and therefore the sorption of P may be described using two-surface Langmuir equation.The process of P desorption had high P concentration.The characteristics of succe.ssrve an evident hysteresis phenomenonn at desorption further indicated the presence of two forms of adsorbed sites or regions,one adsorbed P tightly,another loosely.Organic matter (O.M.) significantly affected P sorbtion by soils.The addition of O.M.could increase the amount of P adsorbed but it could be conductive to P desorption as well.The higher the content of O.M.the more easily the adsorbed P,especially at low P concentration.After O.M.was removed,P was more tightly adsorbed by soils,and therefore the desorption rate decreased evidently.

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夏汉平,高予勤.磷酸盐在白浆土中的吸附与解吸特性[J].土壤学报,1993,30(2):146-157. Xia Hanping, Gao Ziqin. CHARACTERISTICS OF PHOSPHATE ADSORPTION AND DESORPTION IN ALBIC SOILS[J]. Acta Pedologica Sinica,1993,30(2):146-157.

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  • 在线发布日期: 2013-02-25
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