氢醌在土壤水稻系统中的分布、降解和累积
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DISTRIBUTION,DEGRADATlON AND ACCUMULATIONOF HYDROQUINONE IN SOIL-RICE SYSTEM
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    摘要:

    14C-氢醌和15N-尿素为示踪剂,通过棕壤盆栽试验,研究了氢醌在土壤中的分布、存在形态及迁移机制。氢醌的残留量随土壤垂直深度的增加而增多,平均土壤残留量为0.041mg/kg土。由于土壤理化和生化作用,约有13%的氢醌分解成CO2和水。残留于土壤的14C,49%进入土壤高分子有机化合物,不能再被溶剂所提取。实验测定了水稻对氢醌的吸收、分配和代谢。糙米和茎叶中氢醒的含量分别为0.07mg/kg和0.05mg/kg.水稻体内14C-氢醒的90%以上能破代谢和降解。实验表明,外源氢醌参加了植物的碳代谢,并促进了土壤尿素N的利用。根据实验结果,计算了长期使用长效尿素后土壤中氢醌残留量极限值是0.044mg/kg土。该值远小于美国规定的土壤氢醌残留量标准中,保障人体健康所允许的最高临界值0.20mg/kg土,结论是长期使用长效尿素是安全的。

    Abstract:

    Based on pot-experiments with 14C-hydroquinone and 15N-urea, the distribution, forms and transfer of hydroquinone (HQ) in a soil-rice system were discussed. Residues of hydroquinone in soil increased with the soil depth, with an average of 0.041mg/kg. 13% of hydroquinone was decomposed as CO2 and H2O due to biochemical and physiochemical actions. 49% of the residue-14C entered into high moleeular compounds and could not be extracted by solvents, while 45% into low molecular compound. Metabolism, distribution and absorption of hydroquinone in rice were determined. The contents of hydroquinone in brown rice and stem (and leaf) were 0.07mg/kg and 0.05mg/kg respectively. Results of pot-experiment show that exogenous hydroquinone participated in metabolism of C in rice and promoted the utilization of urea-N in soil. Limiting value of hydroquinone residual in soil after long-term application of slow-release urea was calculated to be 0.044 mg/kg, which was far lower than the hydroquinone standard 0.20mg/kg soil for human health in U.S.A. It could be concluded that long-term application of slowreleasing urea is very safe.

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李书鼎,赵晓燕,周礼恺,孟鸿光,杨健秋.氢醌在土壤水稻系统中的分布、降解和累积[J].土壤学报,1994,31(2):138-145. Li Shuding, Zhao Xiaoyan, Zhou Likai, Meng Hongguang, Yang Jianqiu. DISTRIBUTION, DEGRADATlON AND ACCUMULATIONOF HYDROQUINONE IN SOIL-RICE SYSTEM[J]. Acta Pedologica Sinica,1994,31(2):138-145.

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  • 在线发布日期: 2013-02-25
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