红壤粘粒对Co、Cu、Pb和Zn吸附亲和力的研究
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* 国家自然科学基金


STUDY ON ADDORPTION AFFINITIES OF Co, Cu,Pb AND Zn FOR DIFFERENT RED SOIL CLAYS
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    摘要:

    本文研究了高度风化的酸性红壤对Co、Cu、Pb、Zn离子的吸附特性。用吸附曲线形状,吸附方程,分配系数,pH50值等讨论了吸附亲和力特征及其影响因素和吸附反应的机理。结果表明,红壤粘粒吸附重金属离子主要由Fe、Al氧化物所控制。金属离子对红壤粘粒的吸附亲和力(以pH50表示)主要决定于离子本身的化学性质,亲和力以Cu≥Pb>zn>Co顺序减少,易水解的离子吸附亲和力较大,亲和力也受土壤组分及其表面性质影响,含Fe、Al氧化物多的粘粒其表面的反应活性也较大,对金属离子的亲和力较强。通过竞争吸附方程对吸附-pH曲线的描述和分配系数等的讨论,揭示出四种离子与红壤粘粒的反应机理并不相同,Cu、Pb离子以专性吸附反应为主,Zn、Co则非专性吸附占一定比例。对专性吸附机理,可以认为从低pH时的配位机理和水解-吸附机理共存逐渐转为高pH时的水解-吸附机理为主是合理的。

    Abstract:

    An experiment on the characteristics of Co, Cu, Pb and Zn adsorption by seven highly weathered acid soils derived from different parent materials in different areas of southern China was conducted to study affinity characteristics and factors affecting affinity as well as the mechanism of adsorption reaction by using shapes of adsorption curve, pH values and competitive adsorption equations and distribution coeffieients. Clay fractions(< 11tm) separated from red soils with different properties were allowed to react with solutions of Co, Cu, Pb and Zn in 25 ml 0.05 mol/L Ca(NO3)2 as supporting electrolyte containing the desired amount of adsorbate ion, respectively. The pH values of suspention were adjusted by adding appropriate amounts of 0.1 mol/L N03 or saturated Ca(OH)2 solution prior to metal addition to obtain a series of suspentions with various pH values.

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王维君,邵宗臣,何群.红壤粘粒对Co、Cu、Pb和Zn吸附亲和力的研究[J].土壤学报,1995,32(2):167-178. Wang Weijun, Shao Zongchen, He Qun. STUDY ON ADDORPTION AFFINITIES OF Co, Cu, Pb AND Zn FOR DIFFERENT RED SOIL CLAYS[J]. Acta Pedologica Sinica,1995,32(2):167-178.

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  • 在线发布日期: 2013-02-25
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