恒电荷土壤和可变电荷土壤动电性质的研究 Ⅱ.阴离子吸附和pH的影响
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* 国家自然科学基金(49471041,49631010;49771046)


STUDIES ON ELECTROKINETIC PROPERTIES OF CONSTANT CHARGE SOILS AND VARIABLE CHARGE SOILS Ⅱ. EFFECT OF ANION ADSORVTION AND pH
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    摘要:

    本工作研究了阴离子吸附和pH对恒电荷土壤(黄棕壤和黑土)和可变电荷土壤(砖红壤)动电性质的影响。结果表明,砖红壤吸附不同阴离子后的ζ电位随pH升高由正电位移至负电位,在(电位-pH曲线上均有一个等电点(IEP);在pH3.5~8之间,相同pH下,砖红壤的ζ电位随吸附阴离子的负移顺序是HPO42->F->SO42->Cl->NO3-:作为恒电荷土壤的黄棕壤和黑土,在不同电解质溶液中的ζ电位均为负值,没有等电点;ζ电位-pH曲线的形状随土壤、溶液和pH而异。在pH5.5~9之间,黄棕壤和黑土吸附阴离子后ζ电位负移具有相同的顺序:SO42->HPO42-≥F->Cl->NO3-.

    Abstract:

    In this work,effects of anion adsorption and pH on the electrokinetic properties of constant charge soils and variable charge soils were studied. Yellow Brown soil and Phaeozem were used as representatives of constant charge soils, and Latosol was used as representative of variable charge soils.The results showed that the zeta potential of Latosol particles which had adsorbed different anions changed to negative from positive in sign with the increase in pH and an isoelectric point (IEP) occurred on all the zeta potential-pH curves. In the pH range of 3.5-8.0, the absolute value of change in zeta potential of Latosol particles adsorbed different anions was of the order HPO42->F->SO42->Cl->NO3-.The zeta potentials of yellow brown soil and Phaeozem particles referred as constant charge soil were always negative in sign and no IEP occurred on zeta potential-pH curves.The shape of zeta potential-pH curves varied with the soil type, the anion kind and the pH. In the pH range of 5.5-9, the absolute value of change in zeta potential of yellow brown soil and Phaeozem which had adsorbed different anions was of the order SO42->HPO42->F->Cl->NO3-.

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李成保,季国亮.恒电荷土壤和可变电荷土壤动电性质的研究 Ⅱ.阴离子吸附和pH的影响[J].土壤学报,2000,37(1):62-68. DOI:10.11766/trxb199902240108 Li Cheng-bao, Ji Guo-liang. STUDIES ON ELECTROKINETIC PROPERTIES OF CONSTANT CHARGE SOILS AND VARIABLE CHARGE SOILS Ⅱ. EFFECT OF ANION ADSORVTION AND pH[J]. Acta Pedologica Sinica,2000,37(1):62-68.

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  • 收稿日期:1999-02-24
  • 最后修改日期:1999-06-10
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  • 在线发布日期: 2013-02-25
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