塿土不同粒级组分K+吸附研究
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STUDIES ON K+ ADSORPTION OF DIFFERENT FRACTIONS OF LOU SOIL
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    摘要:

    塿土各粒级K+吸附特征有很大区别.在一定平衡液浓度下,颗粒越细,土壤固相吸附量越大,不同粒级固相吸附量大小顺序是:(<0.1μm)>(<1μm)>(1-2μm)>(2-5μm),不同粒级土壤有效阳离子交换量也具有相同的变化规律.混合样中不同粒级组分对吸附的贡献可用吸附贡献率表示,楼土各粒级饱和吸附贡献率大小顺序为:(<1μm)>(1-2μm)>(>5μm)>(2-5μm),其中粘粒部分的饱和吸附贡献率为85%左右.在供试混合土样中<1μm粒级吸附贡献率随平衡液浓度增大呈幂函数形式增大,相反,1~2μm、2-5μm粒级吸附贡献率随平衡液浓度增大则呈幂函数形式减小.实验证明混合样中不同粒级K+吸附存在交互作用,吸附交互作用大小可用吸附交互作用系数表征,<1μm和1-2μm之间存在吸附负交互作用,且随平衡液浓度增大而增强.<1μm和2-5μm之间存在吸附正交互作用,且随平衡液浓度增大而减弱.论述了建立土壤多粒级组分吸附方程的必要性,提出了多粒级组分吸附方程:q=β(c)Σr1f1(c).

    Abstract:

    K+ adsorption of different particle fractions of lou soil varies greatly. At certain equilibrium concentration, the sequence of the amounts of K+ adsorbed in different soil particle fractions is(<0.1 μm)>(<1 μm)>(1-2 gym)>(2-5 μm), the same as that of the effective cation exchange capacity of different soil particle fractions. The contribution of each particle fraction to the total amount of adsorbed K+ is demonstrated by adsorption contribution rate. The order of the saturated adsorption contribution rates of different particle fractions in lou soil is(<1 μm)>(1-2 μm)>(>5 μm)>(2-5 μm), and the adsorption contribution rate of clay fraction attributes to nearly 85% of the total amount. In < 1+1-2 μm,< 1+2-5 μm mixtures, the adsorption contribution rate of <1 μm increases, whereas that of 1-2 μm, 2-5 μm decreases by the power function with increasing equilibrium concentration. The adsorptive interaction of different fractions has been verified. The adsorption interaction coefficient of c, indicating that the adsorption interaction of<1 μm and 1-2 μm fractions is negative, and augments with c increment. The adsorption interaction coefficient of < 1 μm and 2-5 μm fractions is more than 1 and decreases with c increment, which indicates that the adsorption interaction of < 1 μm and 2-5 μm fractions is positive and abates with increasing c. The necessity of setting up the multi-fraction adsorption equation has been confirmed.、multi-fraction adsorption equation is q=β(c)Σr1f1(c).

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王玉,张一平.塿土不同粒级组分K+吸附研究[J].土壤学报,2001,38(2):241-247. DOI:10.11766/trxb199911040213 Wang Yu, Zhang Yi-ping. STUDIES ON K+ ADSORPTION OF DIFFERENT FRACTIONS OF LOU SOIL[J]. Acta Pedologica Sinica,2001,38(2):241-247.

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  • 收稿日期:1999-11-04
  • 最后修改日期:2000-04-17
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  • 在线发布日期: 2013-02-25
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