咪鲜胺及其三种主要代谢物在六种水稻土中的吸附
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* 农业部与德国艾格福公司协作项目(NYBNYCL20000158)


ADSORPTION OF PROCHLORAZ AND ITS MAJOR METABOLITES IN PADDY SOILS
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    摘要:

    用批量平衡法研究了咪鲜胺及其三种主要代谢物BTS44595、BTS44596和BTS45186在六种水稻土中的吸附。结果表明:水稻土以物理吸附作用来吸附咪鲜胺及其代谢物,吸附平衡时间为7~14h,吸附过程可用Freundlich吸附等温式描述。水稻土对咪鲜胺吸附能力均比其代谢物要强,三种代谢物之间的吸附量差异性不是很大。咪鲜胺在水稻土中的吸附与土壤有机质含量、阳离子交换量和粘粒含量成显著正相关,而BTS44595、BTS44596和BTS45186在水稻土中的吸附主要受土壤pH值的控制。这说明咪鲜胺在降解代谢后改变了它在土壤中的吸附行为与吸附机理,对此应予以足够的关注。

    Abstract:

    Adsorption of Prochloraz and its major metabolites,BTS44595,BTS44596 and BTS45186,in six types of paddy soil were studied with the batch equilibrium method.Results show that the paddy soils adsorbed Prochloraz and its metabolites by physical means,and the adsorption process could be represented with the Freudlich isotherm equation.Absorbing capacity of the paddy soils was higher for Prochloraz than for its metabolites,and there was no visible distinction in adsorption amount between the three metabolites.Adsorption of Prochloraz by the paddy soils were positively correlated with organic matter content,cation exchange capacity and clay content,while adsorptions of the three metabolites were restricted by pH values of the paddy soils, suggesting that metabolism of Prochloraz could change its adsorption behavior and mechanism in the paddy soils.Therefore,adequate attention should be paid to that when Prochloraz was applied to the paddy soil.

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龚道新,汪传刚,邹雅竹,杨仁斌,郭正元,樊德方.咪鲜胺及其三种主要代谢物在六种水稻土中的吸附[J].土壤学报,2007,44(1):90-97. DOI:10.11766/trxb200510310114 Gong Daoxin, Wang Chuangang, Zou Yazhu, Yang Renbin, Guo Zhengyuan, Fan Defang. ADSORPTION OF PROCHLORAZ AND ITS MAJOR METABOLITES IN PADDY SOILS[J]. Acta Pedologica Sinica,2007,44(1):90-97.

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  • 收稿日期:2005-10-31
  • 最后修改日期:2006-03-06
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  • 在线发布日期: 2013-02-25
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