Effects of pore-water velocity and pH on Cu，Pb，Zn and Cd transport in quartz sands were studied，through a stable flow miscible displacement experiment，and breakthrough curves(BTCs) of the tracer bromide(Br^-) and Cu/Pb/Zn/Cd were obtained. And their adsorption coefficients were determined through indoors batch equilibrium experiments and then their retardation factors(R_d) were worked out. Based on the results of the experiments with the aid of Software CXTFIT2.1 (A nonlinear least-squares optimization approach) BTC of Br^- was fitted with the equilibrium CDE model，yielding dispersion coefficient (D). On such a basis，BTCs of Cu，Pb，Zn and Cd in conditions of different pore-velocity and pH were fitted with the non-equilibrium CDE model，and dynamics of their concentrations at various depths and in parallel experiment were predicted. Results show that the transport of Cu/Pb/Zn/Cd in quartz sand columns increased with pore-water velocity，but decreased with rising pH. Conclusively，the non-equilibrium-theory-based two-site model describes better transport of Cu，Pb，Zn and Cd in such a scenario as of this experiment.