POTENTIAL LEACHABILITY OF HEAVY METALS IN URBAN SOILS FROM HANGZHOU CITY
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    Abstract:

    The potential risk of surface and ground water contaminat ion by heavy metals leached from contaminated soils have caused considerable concern.Understanding the accumulat ion and chemical forms of the elements in soils is necessary to predict long term leaching behavior of the heavy metals in the soils.The objective of this study was to evaluate heavy metal leachability of urban soils in Hangzhou City, Zhejiang Province, China.A total of twenty urban soils and twelve suburban agricultural soils were collected from the urban and suburban areas in the Hangzhou city for fract ionation and leaching test of heavy metals.An optimized European Community Bureau of Reference three-step sequential extraction procedure was applied to heavy metal fractionation of the soils.Four operationally defined fract ions were identified: acid extractable, reducible, oxidizable and residual.The soils were also subjected to determination of potential leachability of heavy metals using a method developed by the Netherlands Energy Research Center.The results showed that the urban soils in the Hangzhou City had been anthropogenically contaminated by heavy metals to a great extent, and heavy metals in the urban soils, including Cd, Cr, Cu, Ni, Pb, Zn, and Mn, were higher than those in the suburban agricultural soils.About 70% of Cd, Co, Cr, and Ni were associated with residual fraction indicating relative low mobility of the metals in the soils.Of the four remaining heavy metals, Cu and Pb were dominantly associated with oxidizable and reducible fractions with low acid extraction fraction.Zinc and Mn had only one-third of their total concentrations in the residual fraction, but one-fourth in the acid extractable, which is susceptible to release.Potential leachability of all the measured eight heavy metals, defined as the maximum metal pool that may become available for leaching at a constant pH 4, was low and decreased in the following order: Cu > Mn > Cd > Ni > Zn > Pb > Co, Cr.Low potential leachability of the heavy metals in the urban soils was due to their low percentage of acid-extractable fraction of the heavy metals, and relatively high organic matter, iron oxides as well as clay contents that could adsorb heavy metals released from dissolution processes.Measured data indicated a low risk for surface and ground water contamination from the urban soils in the Hangzhou City.

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Zhang Ming-kui, Wang Mei-qing. POTENTIAL LEACHABILITY OF HEAVY METALS IN URBAN SOILS FROM HANGZHOU CITY[J]. Acta Pedologica Sinica,2003,40(6):915-920.

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History
  • Received:April 05,2002
  • Revised:September 02,2002
  • Adopted:
  • Online: February 25,2013
  • Published: